This is the 82nd most frequent Italian word.
lui
"He" or "him."
In this sentence, 'lui' acts as the subject pronoun.
Lui è il mio migliore amico.
He is my best friend.
In this sentence, 'lui' functions as the stressed pronoun for emphasis.
Ho visto lui al parco ieri.
I saw him at the park yesterday.
Here, 'lui' is used as a prepositional pronoun.