This is the 284th most frequent Russian word.
новой
"New" (feminine form).
In this sentence, 'новой' ('new') is declined in the accusative case to match the feminine noun 'машину' ('car').
Я купил новую машину.
I bought a new car.
'Новей' appears in the instrumental case, corresponding to the feminine singular noun 'соседкой' ('neighbor').
Мы познакомились с новой соседкой.
We got acquainted with the new neighbor.
Here, 'новой' is in the prepositional case, agreeing with the feminine singular noun 'книге' ('book').